Table of Contents
How would you prepare phenol from cumene?
To prepare phenol, cumene is first oxidized in the presence of air of cumene hydro-peroxide. Then, cumene hydroxide is treated with dilute acid to prepare phenol and acetone as by-products.
What are phenol How is phenol prepared from cumene?
Preparation of Phenols from Cumene Upon oxidation of cumene (isopropylbenzene) in the presence of air, cumene hydroperoxide is obtained. Upon further treatment of cumene hydroperoxide with dilute acid, phenols are obtained. Acetone is also produced as one of the by-products of this reaction in large quantities.
How will you prepare phenol?
In this method, benzene sulfonic acid is reacted with aqueous sodium hydroxide. The resulting salt is mixed with solid sodium hydroxide and reacted at a high temperature. The product of this reaction is sodium phenoxide, which is acidified with aqueous acid to make phenol.
Which of the following process can be used to prepare the starting compound cumene?
The process of the invention for preparing cumene by reaction of isopropanol with benzene in presence of the catalyst of the present invention makes it possible to prepare cumene in one synthesis step.
HOW IS carboxylic acid prepared from cumene?
Cumene is used in the preparation of phenol. So, phenol can be converted into carboxylic acid with the help of oxidizing agents. The cumene process was invented in 1942 by R. It is an intermediate that formed during the reaction mechanism of conversion from benzene to phenol.
What is the reagent which will react with cumene to give phenol?
cumene hydroperoxide
What is the reagent which will react with cumene to give phenol? Explanation: Upon oxidation of cumene (isopropylbenzene) in presence of air (oxygen), cumene hydroperoxide is obtained. Upon further treatment of cumene hydroperoxide with dilute acid phenols are obtained. 7.
How is carbolic acid prepared from cumene?
Answer: Cumene (isopropylbenzene) is oxidised in the presence of air to cumene hydroperoxide. It is converted to phenol and acetone by treating it with dilute acid.
Which catalyst is used in commercial method of preparation of phenol?
Cobalt naphthenate
-Therefore the catalyst used in the commercial method of preparation of phenol is (D) Cobalt naphthenate.
What is the commercial method of preparation of phenol Dows process from diazonium salt by decarboxylation of salicylic acid Hock method?
Answer: When an aromatic primary amine is treated with nitrous (NaNO2 + HCl) acid at 273 – 278 K, diazonium salts are obtained. Upon warming with water, these diazonium salts finally hydrolyze to phenols.
How is phenol prepared by commercial method?
Explanation: The primary commercial way to produce phenol is by acidic oxidation of cumene. The air oxidation of cumene (isopropylbenzene) leads to the production of both phenol and acetone which are separated by distillation.
What is cumene used for?
Cumene (1-methylethylbenzene) Description. Cumene is used to manufacture other chemicals such as phenol , acetone , acetophenone, and methyl styrene . It is used as a thinner in paints, lacquers, and enamels. It is a component of high octane motor fuels. Cumene in used in the manufacture of rubber, iron and steel, and pulp and paper.
How will you prepare benzene from phenol?
Benzene can be prepared from phenols too through their reduction . In this process vapours of phenol are passed over heated zinc dust. Zinc dust reduces them to form benzene. Benzene can be prepared from sulphonic acids through their hydrolysis.
What are the chemical properties of phenol?
Chemical properties of phenol In alcohols and phenols , -OH group is the functional group. 1) Reactions involving cleavage of -OH bond. In addition to this, phenols react with aqueous sodium hydroxide to form sodium phenoxides.The above reactions show that alcohols and phenols are acidic in nature.
What is the formula of phenol?
Phenol, also known as phenolic acid, is an aromatic organic compound with the molecular formula C6H5OH. It is a white crystalline solid that is volatile. The molecule consists of a phenyl group (−C6H5) bonded to a hydroxy group (−OH). It is mildly acidic and requires careful handling due to its propensity to cause chemical burns.